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At this point, it may be hard to delineate a particular ingredient which may be causing your child's skin condition. If an allergic reaction to the sunblock is being considered it is best to avoid using this. There are hypoallergenic brands in the market and you may opt to use them instead. You may apply a small part in a small area of the forearm or behind the ears before using it on larger areas.
Here is a url which may interest you and guide you with your choice of skin products.
http://lesstoxicguide.ca/index.asp?fetch=personal#sunpr