i would see a doctor to have this examined. it could be the start of vessicular tinea pedis (athlete's feet), contact dermatitis, allergic reaction to chemicals, medication, etc.
OK, now this morning the whole heal of my foot is extremely sore and I cannot walk on it at all. I had to line my shoe with several layers of padding (odor eaters that my husband bought and didn't use yet - but really needs to!) just to get to work. I know I didn't get bit by anything or step on something to hurt it. Should I go see a doctor?