Sry, it's called the morning after pill or emergency contraception. I may wrong about when take it. But the sooner the better!
Sry totally missed the condom part. The spermicide does help lessen the risk. She could take the day after pill to help prevent pregnancy. She needs to take it within at least 72 hours
Risk is low but still very possible depending on her ovulation time and survival of sperm (it takes only one). Next time pls be more responsible and careful if u are not ready for a baby.
The possability is that she could be pregnant - seeing that you finished inside of her!!
Hopefully for your sake i HOPE SHES NOT
Good Luck