No. Day 1 of your period counts as cycle day 1. Most women ovulate mid cycle. So say for example a women who has a 38 day cycle, she will most likely ovulate around cd14. You need to be having sex up until you ovulate to conceive, if you miss ovulation, then you won't conceive. You cannot get pregnant during your period since ovulation has already occurred. Also you won't already be pregnant and be having a period, that's not possible either.
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