I'm not totally sure what you're asking here? Do you mean how can you feel any pleasure (orgasm) when you are used to doing it yourself (masturbating).
If so then usually yes! It depends on the woman, and what techniques/positions the two of you use during sex.
There are some exceptions, which may be because of medication a woman is on or a medical condition that she is unable to reach an orgasm, but that isn't that common.
The best to reach one is for the woman to go on top, where she is able to take control and also the rhythm is good on your clitoris. It is also good for him to use his fingers on it during sex as most woman need this to reach an orgasm during sex too. :)
The clitoris gets a lot of stimulation during sex with a guy. Usually.