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hydroxytryptophan and valerian root

I have a 8 1/2 dane who suffers greatly from anxiety.  She never had a problem until this year. We tried benadryl, xanax, and most recently the dog recommended hydroxy and valerian root.  Does anyone know of a good combo for dogs and dosage for my 113 lb dog.

This was recommended by my vet's co associate who works with a dog's behavior.  She charges $215 an hour which is why I don't have exact dosage info.
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