Pregnancy, thrush, bacterial vaginosis, yeast infection and trichomoniasis all can lead to thick white discharge from vagina.Painful sex can be due to lack of lubrication,vaginismus,ovarian cysts,endomteriosis,pelvic inflammatory disease etc.Since you have missed your periods take up urine pregnancy test. Seeking the opinion of a gynecologist will be really helpful.
Best luck and regards!
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