Sounds like more than the breasts. Does she have access to a counselor or therapist? 200 lovers is a lot in the time between age 14 and getting married, and it suggests she's not getting much out of sex in general. The question would be why, and she could unpack that with the help of a good therapist.
That she had 200 lovers suggests childhood sexual abuse. And so does inability to orgasm with a partner, for women who have the ability to orgasm by themselves.