Regarding that the ileocecal valve (between ileum and colon) was removed, it is possible that colonic bacteria have colonised the small intestine (small intestinal bacterial overgrowth). Remind the doctor of this possibility, since this is often overlooked.
Leg cramps and weakness are characteristic in hypokalemia. So serum potassium has to be checked (all other electrolytes will be checked at the same time routinely).
Eventual vitamine supplements should be prescribed on a basis of vitamin levels in the blood. Fat soluble vitamins (A,D,E,K) are probably malabsorbed, since fat is obviously malabsorbed. In ileum removal (as in your wife case) folate and vit B12 are usually malabsorbed.
Foamy urine is probably due to excess protein excretion in urine (kidney failure).
If she can't be hydrated properly with the plain water, then she should take some salt and sugar with the fluid, what greatly improves water absorption. There are many possibilities: sport drink, like Gatorade, rehydration solutions like Pedialyte, Rehydralyte...or the solution may be prepared at home.
Do not in any case try with any supplements without prior doctor's evaluation.
She needs:
1. Serum electrolytes, urea, proteins check.
2. Replacment of electrolytes, proteins, vitamins, water...as decided by a doctor.
Hypokalemia may be life dangerous, it may cause arrhythmia, so I suggest prompt visit of a doctor.